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991.
992.
993.
Lianqing Chen Jingui Qin Jia Gao Dongge Ma 《Journal of organometallic chemistry》2006,691(16):3519-3530
Four new iridium(III) complexes 1-4, with 1,3,4-oxadiazole derivative as cyclometalated ligand for the first time, have been synthesized and structurally characterized by NMR, EA, MS and X-ray diffraction analysis (except 1). The stronger ligand field strength of the dithiolate ancillary ligands results in higher oxidation potentials and lower HOMO energy levels of complexes than acetylacetone. The absorption spectra of these complexes display low-energy metal-to-ligand charge transfer transition ranging from 350 to 500 nm. Complexes with dithiolate ancillary ligand emit at maximum wavelengths of ca. 500 nm, blue shifting 17 and 11 nm with respect to their counterpart with acetylacetone ligand. The electrophosphorescent devices with 2-4 as phosphorescent dopant in emitting layer have been fabricated. All devices have a low turn-on voltage in the range of 4.5 and 4.9 V. A high-efficiency green emission with maximum luminous efficiency of 5.28 cd/A at current density of 1.37 mA/cm2 and a maximum brightness of 2592 cd/m2 at 15.2 V has been achieved in device using 2 as emitter. 相似文献
994.
The separation and determination of Os(IV), Ir(IV), Pt(II), Ru(III), Co(II) and Ni(II) complexes with 2-(6-methyl-2-benzo-thiazolylazo)-5-diethylaminophenol (MBTAE) was studied on RP-HPLC. The effects of methanol concentration, pH-value of the mobile phase, column temperature (T), total flow rate and foreign ions on the retention behaviour have been investigated in detail. It has been shown that the logarithm of the capacity factor (ln k) is in linear relation to the methanol concentration of the mobile phase and the reciprocal of the column temperature (T). The six complexes can be separated within 30 min in a methanol-buffer system. 相似文献
995.
Cationic polyaspartamides including poly-α,β-[N'-(2-aminoethyl)-L-aspartamide] (PAEA), poly-α,β-[N'-(4- aminobutyl)-L-aspartamide] (PABA), poly-α,β-[N'-(6-aminohexyl)-L-aspartamide] (PAHA), poly-α,β-[N'-(5-amino- 3-azapentyl)-L-aspartamide] (PAAPA) and poly-α,β-[N'-(8-amino-3,6-diazaoctyl)-L-aspartamide] (PADAOA) were synthesized from polysuccinimide. Their properties were evaluated by ^1H NMR, IR, GPC, fluorescence measurement and in vitro cytotoxicity assays. The molecular weights per primary amine charge group of PAEA(1) (Mn= 2229), PAAPA and PADAOA are 212, 279, and 226. Polyaspartamides including PAEA(1), PAAPA, PADAOA and low molecular weight PAHA are markedly less toxic than poly(ethyleneimine) and poly(L-lysine), however, PABA and higher molecular weight PAHA are slightly less toxic than poly(L-lysine). Cell cytotoxicity of PAHA was seen to decrease with increasing molecular weight of PAHA, due to water solubility reduction. The negatively charged plasmid DNA has been found to be completely neutralized and complexed by the cationic polyaspartamides at an N/P ratio of 5 : 1 to 10 : 1, forming self-assembled polyplexes via ionic interactions. These polyaspartamide/DNA complexes possess stable zeta potentials and mean particle diameters of about 180 nm for PAEA (1)/DNA and PAAPA/DNA complexes and 280 nm for PADAOA/DNA complexes. 相似文献
996.
本文以四-(对氨基苯基)卟啉和N-氯乙酰缬氨酸为原料,在DMF中首次合成了一种新型的含二肽基团的四苯基卟啉,四-(对甘-缬二肽苯基)卟啉(H2L),及其Mn(Ⅲ)、Fe(Ⅲ)、Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)、Zn(Ⅱ)配合物MnLCl, FeLCl, CoL, NiL, CuL, ZnL,用元素分析、红外光谱、电子光谱、荧光光谱、氢核磁共振谱和激光拉曼光谱进行了表征,研究了这些新型配合物与含N、S碱的轴向加合性质。 相似文献
997.
Introduction(R ,S) and (S ,S) pyrrolidine 2 carboxylicacid 3,5 dioxa 4 boracyclohepta[2 ,1 a ;3,4 a′]dinaphthalen 4 ylesters ,namely (S) and (R) 1,1′ bi 2 naphtholboricacid (S) prolineanhydrides [(R ,S) BNBAPand (S ,S) BNBAP],areintermediatesinthepreparationofver satilechiralauxiliariesenantiopure 1,1′ bi 2 naphthols .1Recently ,itwasobservedthattheycouldcatalyzeanum berofasymmetricreactions .2 Therefore ,itisimportanttodevelopamoreconvenientproceduretoprepare .Previou… 相似文献
998.
Yan S Huang R Zhou Y Zhang M Deng M Wang X Weng X Zhou X 《Chemical communications (Cambridge, England)》2011,47(4):1273-1275
In this thrombin detection system, the bright fluorescence of TASPI is almost eliminated by the DNA aptamer TBA (turn-off); however, in the presence of thrombin, it specifically binds to TBA by folding unrestricted TBA into an anti-parallel G-quadruplex structure and then releasing TASPI molecules, resulting in vivid and facile fluorescence recovery (turn-on). 相似文献
999.
Chun Hai Yang Cheng Guo Hu Sheng Shui Hu 《中国化学快报》2007,18(3):313-315
Stable adsorption and direct electrochemistry of glucose oxidase (GOx) occurred on nitric acid (HNO3)-treated multi-walled carbon nanotubes (MWNTs) instead of as-received MWNTs, demonstrating the critical roles of oxygen-containing groups in stableadsorption and direct electrochemistry of GOx on carbon nanotubes (CNTs). 相似文献
1000.
Wu Feng Deng Nansheng E. M. Glebov I. P. Pozdnyakov V. P. Grivin V. F. Plyusnin N. M. Bazhin 《Russian Chemical Bulletin》2007,56(5):900-903
The formation of MV•+ radical cations was observed upon the laser flash photolysis of the iron(III) tartrate complex [FeIIITart]+ (1) in the presence of methyl viologen (MV2+). The rate constants of the reactions involving MV•+ were measured. The intramolecular electron trans-fer to form FeII and escape of the organic radical to the solvent bulk upon the photolysis of 1 were proposed.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 866–869, May, 2007. 相似文献